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White light through a grating

The zero order is white, because all wavelengths have zero path difference there. Every higher order is a continuous spectrum, with violet closest to the centre and red furthest out, since d sin θ = nλ means longer wavelength deviates more. Higher orders can overlap, for example the red end of the second order can fall beyond the violet end of the third order.

sin θ = nλ/d, so θ increases with λ at fixed n

What this actually means

This is the opposite way round from a glass prism, where violet is deviated most. A grating disperses by path difference, a prism by refractive index, so the colour order reverses. Examiners love this contrast.

Explain the white centre properly: at n = 0 the path difference is zero for every wavelength, so all colours interfere constructively at the same place and recombine to white.

For the overlap question, compute the extreme angles. With d = 1.67 µm, the second order red (700 nm) is at 57.1° while the third order violet (450 nm) is at 54.1°, so the third order violet appears before the second order red has finished. That is a genuine overlap.

Each spectrum also gets wider with order, because the angular gap between violet and red grows with n. The first order might span 11°, the second 24°.

Draw it as a fan, symmetric about the centre: white line in the middle, then violet-to-red spectra spreading outwards on both sides, getting broader and fainter.

The trap

Putting red nearest the centre by copying the prism spectrum. On a grating the longest wavelength deviates most.

Prove it — watch it be true

  1. Switch the source to white light and observe the fanned spectra.
  2. Confirm the central maximum is white and that in every higher order violet sits closest to the centre.
  3. Increase the order and confirm the second and third order spectra begin to overlap.
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